Switching between org. and personal logins on the desktop app.

When I use my browser it has passwords saved for both my organizational and personal login (under the same account), but with the MacOS app I have to keep typing passwords in manually when I switch back and forth. Can't seem to find a way to change that and have both passwords retained by the app. Please help.

This is the 2nd time I've tried to get help with this and got no reply last time. I've no idea if this is the right place to submit this, but can't find anything else that fits at all.